Latest Publications
Table of Contents
Closing the loop: recycling of MAPbI3 perovskite solar cells (Energy & Einvironmental Science, 2024)
Closed-loop recycling is crucial in the rapidly expanding era of photovoltaic deployment. Yet, the recycling of commercial silicon photovoltaic modules presents challenges due to laborious component separation. In contrast, layers in solution-processed solar cells can be separated with relative ease through selective dissolution. In this study, we report on the recovery of every layer in a planar MAPbI3 perovskite solar cell using a layer-by-layer solvent extraction approach, followed by purification or modification to restore quality. This method potentially allows for up to 99.97% recycled mass, thereby conserving resources and reducing waste. We assessed material quality by substituting each fresh material with its recycled equivalent during solar cell production. Subsequently, solar cells were fabricated with either several or all layers comprising recycled materials. Every combination yielded efficiency comparable to cells constructed exclusively with fresh materials, demonstrating the efficacy of the developed recycling process. Our mass and value analysis highlights ITO glass has the highest recycling priority and the need for circular utilization for by-product chemicals, especially cleaning agents. Techno-economic projections suggest that the proposed recycling procedure has the potential to afford substantial cost savings. In the lab, recycling could reduce material costs by up to 63.7%, in industrial manufacturing by up to 61.4%. A life cycle assessment reveals this recycling method can reduce environmental impacts.
Cradle-to-cradle recycling in terawatt photovoltaics: A vision of perpetual utility (Joule, 2024)
To achieve carbon neutrality, a significant increase in photovoltaic module production is needed, affecting material demand and recycling perspectives. Circular recycling is essential for managing the material flows of a multi-terawatt global photovoltaic fleet. Immediate action is required to prevent the accumulation of millions of tons of low-value waste. Circularity’s importance is multi-faceted and varies across materials. Limited silver reserves and competition with other markets necessitate reducing or substituting silver. For polymers, constrained production capacities can also be mitigated through circular recycling. The photovoltaic industry’s immense glass demand calls for circular recycling to avoid overwhelming alternative markets. Recycling silicon, aluminum, and copper is vital for the economic feasibility of recycling, especially if silver is replaced. Although prolonging module lifespan reduces yearly material needs and influx into the recycling stream, it might also postpone achieving carbon reduction goals.
Photovoltaics at multi-terawatt scale: Waiting is not an option (Science, 2023)
A major renewable-energy milestone occurred in 2022: Photovoltaics (PV) exceeded a global installed capacity of 1 TWdc. But despite considerable growth and cost reduction over time, PV is still a small part of global electricity generation (4 to 5% for 2022), and the window is increasingly closing to take action at scale to cut greenhouse gas (GHG) emissions while meeting global energy needs for the future. PV is one of very few options that can be dispatched relatively quickly, but discussions of TW-scale growth at the global level may not be clearly communicating the needed size and speed for renewable-energy installation. A major global risk would be to make poor assumptions or mistakes in modeling and promoting the required PV deployment and industry growth and then realize by 2035 that we were profoundly wrong on the low side and need to ramp up manufacturing and deployment to unrealistic or unsustainable levels.
Cradle to cradle Recycling of Perovskite Solar Cells (IEEE 50th Photovoltaic Specialists Conference (PVSC), 2023)
Cradle-to-cradle recycling plays an important role in resolving one of the major upcoming challenges for photovoltaics in the energy transition – resource management. As photovoltaic production continues to grow, it absorbs a vast amount of resources. Cradle-to-cradle recycling is essential to keep these resources available perpetually and minimize waste generation. To achieve this, a new design paradigm for solar panels that puts recycling in its center is needed. In this study, we show first results of a perovskite solar cell that was created using such a design paradigm. We created a device with 18.1% efficiency and an architecture that facilitates disassembly of the functional layers. We show that the absorber material, MaPbI3 was used for the test device, can be recycled without causing a loss of solar cell efficiency.
Optimizing Perovskite Thin-Film Parameter Spaces with Machine Learning-Guided Robotic Platform for High-Performance Perovskite Solar Cells (Adv. Energy Mater. 48/2023)
Simultaneously optimizing the processing parameters of functional thin films remains a challenge. The design and utilization of a fully automated platform called SPINBOT is presented for the engineering of solution-processed functional thin films. The SPINBOT is capable of performing experiments with high sampling variability through the unsupervised processing of hundreds of substrates with exceptional experimental control. Through the iterative optimization process enabled by the Bayesian optimization (BO) algorithm, the SPINBOT explores an intricate parameter space, continuously improving the quality and reproducibility of the produced thin films. This machine learning (ML)-guided reliable SPINBOT platform enables the acceleration of the optimization process of perovskite solar cells via a simple photoluminescence characterization of films. As a result, this study arrives at an optimal film that, when processed into a solar cell in an ambient atmosphere, immediately yields a champion power conversion efficiency (PCE) of 21.6% with satisfactory performance reproducibility. The unsealed devices retain 90% of their initial efficiency after 1100 h of continuous operation at 60–65 °C under metal-halide lamps. It is anticipated that the integration of robotic platforms with the intelligent algorithm will facilitate the widespread adoption of effective autonomous experimentation to address the evolving needs and constraints within the materials science research community.
The role of innovation for economy and sustainability of photovoltaic modules (iScience, 2022)
The role of innovation for the success of photovoltaics cannot be overstated. Photovoltaics have enjoyed the most substantial price learning of any energy technology. Innovation affects photovoltaic performance in more ways, though. Here, we explore the role of innovation for economics and greenhouse gas savings of photovoltaic modules using replacement scenarios. We find that the greenhouse gas displacement potential of photovoltaic modules has improved substantially over the last 20 years—4-fold for the presented example. We show that the economically ideal time for repowering is after around 20 years, but that repowering may reduce greenhouse gas savings. Expanding photovoltaic installations is generally preferable, economically and sustainably, to repowering. We argue that i) we should maximize the greenhouse gas saving potential of each module, which requires a global strategy, ii) tandem solar cells should aim for stability, and iii) efforts to continue and accelerate innovation in photovoltaic technology are needed.
The value of stability in photovoltaics (Joule, 2021)
Warranties for photovoltaic modules last 25 years. The same duration is frequently used when predicting economic performance. Yet, many modules still produce more than 80% of their original power after 25 years, and there is no economic reason to retire them. Here, we adopt a different mindset: photovoltaic installations are operated indefinitely with maintenance at regular intervals. We reflect this view in a steady-state economic model. We find that in this view, maintenance gains in value—33% compared with a 30-year lifetime—and time constraints for maintenance are lifted. We also find that stability becomes even more important. Reducing annual degradation from 0.5% to 0.2% entails a 12 ct/Watt cost entitlement, increases the economically useful lifetime by a factor of 1.69, defers end of life by decades, and reduces resources and infrastructure needed for recycling by 40%. We foresee that modules installed today should ideally be operated for 50 years.